Orange Oil

Identification of the Substance and Supplier

Identification of the Product	Winterized Orange Oil, Orange Peel Oil
Trade Name	Winterized Orange Oil, Ventura Coastal Corporation P/N 2151513, 215150
Type of product and use	Natural flavoring for the manufacture of beverages, fragrance ingredient
Company identification	Ventura Coastal LLC 2325 Vista Del Mar Drive Ventura, CA 93002
International Emergency Phone Number	(703) 527-3887 (Call Collect)

Hazards Identification

Hazard Designation	F Flammable Xi Irritant Xn Harmful N Dangerous for the environment
Hazard Classification	R10 Flammable R38 Irritating to skin. R43 May cause sensitization by skin contact R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment R65 Harmful: may cause lung damage if swallowed
GHS Label Elements	Warning H226 – Flammable liquid and vapor Danger H304 – May be fatal if swallowed and enters the airways Warning H410 – Very toxic to aquatic life with long lasting effects Warning H315 – Causes skin irritation, H317 – May cause an allergic skin reaction
Prevention	P210 – Keep away from heat, sparks, and open flames. No smoking P241 – Use explosion-proof electrical equipment
Response	P301+P310 – IF SWALLOWED: Immediately call a POISON CENTER or doctor P303+P361+P353 – IF ON SKIN OR HAIR: Remove all contaminated clothing. Use shower or rinse skin/hair with water
Storage	P405 – Store locked up (in a cool place, away from direct sunlight)
Disposal	P501 – Dispose of contents/container in accordance with local, regional, national, and international regulations

Composition/Information On Ingredients

Substance/Preparation	Substance
Ingredient Name WT% CAS No. EINECS No. Orange Oil, Sweet 100% 8028-48-6 232-433-8
Chemical Characterization	Essential oil content 100%, with >92% % d-limonene

First Aid Measures

After inhalation	If overcome by exposure, remove victim to fresh air immediately. Seek medical attention.
After skin contact	Wash skin thoroughly with mild soap/water. Seek medical attention if ill effect or irritation develops.
After eye contact	Remove any contact lenses at once. Flush eyes well with large quantities of water for at least 15 minutes. Seek medical attention.
After swallowing	Do not induce vomiting; immediately call for medical help.

Firefighting Measures

Extinguishing media	Water, carbon dioxide, dry chemical or foam
Special exposure hazards	When heated to dryness and decomposition under fire conditions, this product may release carbon monoxide, carbon dioxide, and other decomposition products of undetermined hazard.
Protect against fire	As with any fire situation, full face, self-contained breathing apparatus and appropriate protective clothing should be worn.

Accidental Release Measures

After spillage/leakage	NO SMOKING. Eliminate other ignition sources. Leaking containers should be moved to a dry well-ventilated area. Isolate spill area. Provide clean-up workers with protective clothing and, when necessary, chemical resistant gloves equivalent to Neoprene/PVC. Keep unnecessary and unprotected personnel from entering. Absorb spillage on sand or vermiculite and place in closed container. Safety glasses with side guards should be worn to prevent injury from flying particles and/or other eye contact with this product.
Waste Handling, Disposal	Dispose of absorbed spillage according to local regulations. Store contaminated absorbent material in a cool place out of the direct sunlight and away from ignitions sources as it is flammable.
Environmental Precautions	Water polluting material. Maybe harmful to the environment if released in large quantities. Prevent entry into sewers, and water courses. Inform appropriate authorities if entry of spillage into sewers/water courses cannot be prevented.

Handling and Storage

Handling	Avoid eye and skin contact. Protect against physical damage to containers. As with all semi-finished materials, prudent industrial practices should be employed to minimize contact with eyes, skin and mucous membranes. Do not use compressed air to transfer contents of container.
Storage	Store in closed containers away from heat, caustics and oxidizing materials or any sources of ignition. Store in original container protected from direct sunlight, in a cool area. Keep container tightly closed and sealed until ready for use Avoid release to the environment. Emptied containers retain product residue and should be considered hazardous.

Exposure Controls/Personal Protection

Ingredients with Limit Values	This product does not contain any ingredients with critical values that need to be monitored in the workplace.
Personal protection	Respiratory protection: Approved respiratory protection recommended in confined areas Skin Protection: Use skin protection appropriate to the conditions of use. Hand Protection: Wear suitable gloves resistant to chemical penetration. Eye Protection: Safety glasses with side guards should be worn to prevent injury from flying droplets and/or other eye contact with this product. Respiratory Protection: Use suitable respiratory protective device when aerosol or mist is formed.
Other	Adequate ventilation is recommended. Keep away from heat & open flame.

Physical and Chemical Properties

Appearance	Physical state: Clear liquid Color: orange Odor: Citrus
Physical Data	Initial boiling point: 171º C/760 mm Apparent Density at 20º C (kg/L): 0.9 Vapor pressure at 55º C *kPa): < 50 Solubility: Insoluble water, soluble alcohol pH value: not applicable Flash point: 50º C, Closed Cup

Stability and Reactivity

Chemical Stability	Stable
Hazardous Polymerization	Will not occur
Conditions to Avoid	Avoid release to the environment. Refer to special instructions
Incompatibility	Strong alkalis, acids and strong oxidizing agents
Hazardous combustion or decomposition products	Carbon monoxide, carbon dioxide

Toxicological Information

Potential Acute Health Effects	Skin contact: May cause skin irritation. Can cause skin photosensitization. May be harmful if absorbed through the skin. Eye contact: May cause eye irritation. May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Inhalation: May be harmful if swallowed. Irritating to mouth, throat and stomach
Acute Toxicity	RTECS #: R18600000 (Oil of Orange) Irritation Data:Skin Rabbit 500 mg/24H Moderate FCTXAV 12,733,1974 Mutation Data: Msc Mouse 120000 ug/L/48H mg/Kg HPV304 --,--,2002 Reproductive Effects: Oral Rat 12375 mg/Kg HPV304 --,--,2002 Tumorigenic Effects Data: Oral Mouse 67 mg/kg/40W-I FCTXAV 35,771,1965 Toxicity Data: * Oral Rat LD50 >5000 mg/kg HPV304 --,--,2002, * Skin Rabbit LD50 >5000 mg/kg HPV304 --,--,2002
Over-exposure signs/symptoms	Skin: Adverse symptoms: irritation, redness, redness Eye: No specific information or data Inhalation: No specific information or data Ingestion: No specific information or data
* Only selected registry of toxic effects of chemical substances (RTECS) data is presented here. See actual entry in RTECS for complete information.

Ecological Information

Environmental Effects	Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Biodegradability	Naturally occurring d-limonene is the principal component of orange oil and is biodegradable; 100% 21 days.
Mobility	Accidental spillage may lead to penetration in the soil and groundwater. However, there is no evidence that this would cause adverse ecological effects.
Other Environmental Effects	No specific information or data

Disposal Considerations

Disposal	This product should be handled in accordance with instructions given under Sections 6, 7 and 8. Dispose of in accordance with National and Local laws. Disposal of surplus product via a licensed waste disposal contractor only.

Transportation Information

General	Handle in accordance with instructions given in Sections 5, 6, 7 and 8. This product should be considered hazardous for domestic shipment by air and non-hazardous for domestic shipment by ground.
International Transport	UN number: UN 1197; extract, flavoring, liquid. Packaging group III. Hazard class 3 (air), 3.3 (vessel).
Marine pollutant	Yes. Orange oil contains 92-97% d-limonene (dipentene), which is listed as a marine pollutant

Regulatory Information

Inventory Status	Listed on TSCA (orange oil, sweet), EINECS/ELINCS (orange, ext.). Classified in Accordance with EC Commission Directive 67/548/EEC on substances.
U.S. Regulations	OSHA—considered hazardous by definition of Hazard Communication Standard (29CFR 1910:1200) FEMA number 2825 US FDA: generally recognized as safe U.S. Superfund Amendments and Reauthorization Act (SARA) Title III: This product is not listed in SARA 313 Toxic Release Chemicals.
German Regulations	Regulations governing combustible liquids (German-VbF) class: AI German water endangering class (WGK) = 1, slightly waterendangering product (manufacturer classification.)
EU Risk(R),Safety(S)	Xn N - Harmful, Dangerous for the environment. R 10 - Flammable. R 36/38 - Irritating to skin and eyes. R 43 - May cause sensitisation by skin contact. R 50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R 65 - Harmful: may cause lung damage if swallowed. S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 61 - Avoid release to the environment. Refer to special instructions/safety data sheet. S 62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label S07 – Keep container tightly closed. S16 – Keep away from sources of ignition – No Smoking. S36 – Wear suitable protective clothing S 37/39 - Wear suitable gloves and eye/face protection.

Other Information

The contents of this SDS are written by the manufacturer, Ventura Coastal LLC, in accordance with the UN Globally Harmonized System of Classification and Labeling of Chemicals (GHS) and with reference to the requirements of EC Commission Directive EU 1272/2008

While The Company believes that the data contained herein are factual, the data are not to be taken as a warranty or representation for which The Company assumes legal responsibility. They are offered solely for your consideration, investigation and verification. Any of these data and information must be determined by the user to be in accordance with applicable National and Local Laws and Regulations. Ventura Coastal LLC makes no warranty of any kind, express or implied, concerning the safe use of this material in your process or in combination with other substances.